Structure of tert.-Butyl Anion

The tert.-butyl anion is sp3 hybridized and assumes a pyramidal geometry. Note that all the methyl groups are oriented in such a way that one C-H bond of each methyl groups is "anti-periplanar" to the C-lone pair.


Figure. The MP2(full)/6-31+G* optimized structure of tert.-butyl anion.