Structure of N,N-Dimethyl Formamide

N-Substitution of Amides. Part 3: N,N-Dimethyl Formamide, HCON(CH3)2.
Primary, secondary and tertiary amides carry 2, 1 or 0 H-atoms on the amide N-atom. Hence the IR spectra will contain 2, 1 or 0 peaks in the region of the NH-stretching vibrations. The molecules HCONH2, HCONHCH3 and HCON(CH3)2 nicely exemplify the effects of N-substitution. Look for their CO stretching frequencies in the output files behind the links "Freqs".


Figure. The MP2(full)/6-31G* optimized structure of N,N-dimethyl formamide.