meta-chloroperoxybenzoic acid - MCPBA

Peroxyacids have the formula R-CO-O-O-H; the -OH group in carboxylic acids is replaced by the -OOH group. Peroxyacids are reagents that can be thought of as delivering oxygen atoms. Meta-chloroperoxybenzoic acid, abbreviated MCPBA, has long been used as the reagent of choice since it was unusually stable and easy to handle.


Figure. The RHF/6-31G* optimized structure of MCPBA.