MU Chemistry 416
FS97
Literature List on Shielding I
Local Contributions
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NMR Shielding and the Periodic Table.
Gerothanassis, I. P.; Kalodimos, C. G.
J. Chem. Educ. 1996, 73, 801-804.
A useful discussion of trends of diamagnetic and
paramagnetic shielding across the periodic table. This article offers a
lot in terms of quantifying ranges and magnitudes. A must study!
Coupled-cluster calculations of nuclear magnetic resonance chemical
shifts.
Gauss, J.; Stanton, J. F.
J. Chem. Phys. 1995, 103(9), 3561-3577.
Do not worry about the theory in this paper. Go right for the good
stuff, the numbers in the tables toward the end.
Benzenediazonium Ion. Generality, Consistency, and Preferability
of the Electron Density Based Dative Bonding Model.
Glaser, R.; Horan, C. J.
J. Org. Chem. 1995, 60, 7518-7528.
Contains a useful discussion that stresses that chemical shifts in
13C- and 14,15N-NMR have nothing to do with atomic
charge.
Electron excitation effects on NMR shieldings in small organic
molecules.
Augspurger, J. D.; Dykstra, C. E.
Chem. Phys. Lett. 1995, 238, 199-202.
This article gives you some information about the kinds of organic
molecules that will give large electron excitation effects.
An Improved Experiment to Illustrate the Effect of
Electronegativity on Chemical Shift.
Boggess, R. K.
J. Chem. Educ. 1988, 65, 819-820.
Electronegativity effects on H-NMR as discussed in lecture.